Regarding the borderlands 2 download content can you play anytime as long as you are a high enough level. I’m currently level 67, which download content would offer the best weapons. Even at being such a high-level Marcus does not offer decent weapons.
Does the borderlands 2 DLC content have anything to do with the main storyline (like the 1st game did).
All DLC’s have separate storylines that you can play without completeing the main story. They refer to the main story in dialogue, so there are some spoilers here and there. That’s obviously not a problem in your case, since you’re at lvl 67. They all contain really great guns and gear, so you should definetly do them all to get your hands on those items.
Examples:
Pirate dlc - Pimpernel (sniper) and Sandhawk (SMG) are both quest rewards and are the best of their types. One of the raid bosses, Hyperius, has a chance to drop the Norfleet (Launcher)
Torgue dlc - Farm Torgue tokens and then farm the Torgue vending machines for a DPUH (Pistol)
Hammerlock dlc - Chance to get the Rough Rider (shield) and the raid boss, Voracidous, has a chance to drop the Interfacer (shotgun)
Tiny Tina dlc - Antagonist and Blockade (both shields) and Grog Nozzle (pistol)
The Headhunter packs also offer some easy farming for legendaries, but those are random.
Apart from all those items, which are all considered as top gear, there’s also a lot of fun in the storylines. I probably missed some of the items, but those items alone makes it all worth the effort.
Thanks I gave some a run through last night just surprised that Marcus inventory is s crappy compared to DLC
Marcus is a greedy person, so he doesn’t sell the good stuff. 
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